Disposal of wastes containing chlorinated paraffins
There are three possibilities:
- resource recovery (reuse/recycling or recovering of energy by
incineration)
- destructive incineration
- landfill
For more information about those three possibilities, see
the
Impact of chlorinated paraffins in recovery/disposal process
page
Each type of waste may be safely managed by one or more of these
techniques. Recommendations are as follows (local regulations
should be consulted to ensure compliance):
Solids
- C10-13 liquids adsorbed onto solids - Hazardous
waste landfill or Incineration.
- C14-17, C18-20, C20-30 solid
and liquid CPs absorbed onto non-combustible solids -
Landfill.
- C14-17, C18-20, C20-30 solid
and liquid CPs adsorbed/ absorbed onto combustible solids -
Incineration or landfill.
- Metal swarf with CPs - Incineration/re-smelting or
Degreasing/separation from solvent or Incineration.
Oil based liquids
- Used oil from metal working operations - Recovery (restrictions
in Germany) or Incineration.
- Mixed plasticiser condensates - Recovery/deodorisation/re-use
when feasible or Incineration.
- Unusable liquid CPs - Incineration.
Water based liquids
Emulsions and mixtures should first be split into oil and water
phases. The oil phase should then be disposed of by incineration.
Three techniques can be utilised in the splitting process producing
split waste of differing quality.
1. Chemical splitting
This gives split water with high salt contents and imperfect oil
separation so that further treatment is required. The oil phase
also is contaminated with chemicals, water, etc. and is
consequently treated as "hazardous waste". Mineral oils can also be
carcinogenic.
2. Aqueous evaporation
The water is evaporated and when condensed often requires no
additional treatment (unless contaminated by volatile substances).
The oil phase can be disposed of by normal incineration/energy
generation (according to calorific value).
3. Ultrafiltration
The separated water may need some additional treatment e.g., to
reduce Chemical Oxygen Demand (COD). The oil phase can be treated
as given for "aqueous evaporation".
Sludges
Three phase mixtures (oil, water and solids) of this type are
best disposed of as hazardous waste by a specialist contractor.
Alternatively a combination of the above separation processes may
be employed by large companies with their own facilities.
Last update: 09/2011