The membrane cell process
electric connection points of each chlorine production cell, the
anode and the cathode, are separated by an ion-exchange membrane.
Only sodium ions and a little water pass through the membrane.
The brine is de-chlorinated and re-circulated. Solid salt is
usually needed to re-saturate the brine. After purification by
precipitation-filtration, the brine is further purified with an ion
View the animated membrane cell
The caustic solution leaves the cell with about 30%
concentration and, at a later stage in the process, is usually
concentrated to 50%. The chlorine gas contains some oxygen and must
often be purified by liquefaction and evaporation.
The consumption of electric energy is the lowest of the three
processes and the amount of steam needed for concentration of the
caustic is relatively small (less than one tonne per tonne of
Chlorine producers across Europe are progressively moving
towards this method of making their product as the membrane cell
process is the most environmentally sound way of manufacturing
chlorine. In 2011, membrane cell capacity accounted for 51% of
total installed chlorine production capacity in Europe.
Click on the image below to have a full size view of the
membrane cell process' animation.
Download a picture of the membrane cell process (PDF). The
PDF images may be used in scientific or technical publications if
the source www.eurochlor.org is
Last update: 02/2013